Verfahren zur Herstellung von Monoepoxiden und tert. Butylalkohol mit einem regeneriertem Katalysator
摘要
Preparation of tertiary butyl alcohol and a linear C3-C12 mono epoxide by the epoxidation reaction of a linear C3-C12 alpha mono olefin with tertiary butyl hydroperoxide in solution in tertiary butyl alcohol in the presence of a catalytic amount of a soluble complex of molybdenum with ethylene glycol, wherein a portion of the catalyst that is used is a recycle (final) ethylene glycol solution of a complex of ethylene glycol with ammonium-containing molybdenum compounds prepared from ethylene glycol and a precipitate of solid ammonium-containing molybdenum compounds formed by saturating a heavy distillation fraction with ammonia to thereby form a liquid amination product containing a precipitate of solid ammonium-containing molybdenum compounds; the heavy distillation fraction being obtained by distillation of the epoxidation reaction product. <IMAGE>
申请公布号
DE69301347(D1)
申请公布日期
1996.02.29
申请号
DE1993601347
申请日期
1993.07.26
申请人
TEXACO CHEMICAL, INC., HOUSTON, TEX., US
发明人
MARQUIS, EDWARD THOMAS, AUSTIN TX 78758, US;MEYER ROBERT ALLEN, MEYER ROBERT ALLEN, BALLWIN MO 63021, US