Process for the preparation of aliphatic and cycloaliphatic oximes

摘要

The prodn. of aliphatic and cycloaliphatic oximes (1) comprises reacting the corresp. imine (2) with oxygen or oxygen-contg. gas in the presence of a catalyst, except for catalysts of formula (Tix(M*D1-x)(2n/3*E1-x))O2 (I), where D = Si or Ge; E = Ce of Al; x = 0.06-0.9; m = 1 if n = 0; m = 0 if n = 1. Also claimed is a process for the prodn. of (1) comprising (a) imination of the corresp. ketone with ammonia by known methods followed by (b) catalytic oxidn. of the imine as above.