发明名称 Process for producing olefin polymers
摘要 A process for producing an olefin polymer which Comprises homopolymerizing or copolymerizing an olefin in a gas phase by using a catalyst system comprising the following components A) and B): A) a solid catalyst component prepared by immobilizing a catalyst component comprising at least titanium, magnesium, halogen and an electron-donative compound on a porous polymer material, said solid catalyst component satisfying the following conditions (a), (b) and (c): (a) ethylene is preliminarily polymerized thereon in an amount of 50-200 g per gram of the component previously immobilized on the porous polymer material. (b) the preliminary polymerization of ethylene is carried out at most at a rate of 3 g/g-immobilized component-hour at least until the quantity of the preliminarily polymerized ethylene reaches 5 g/g-immobilized component, and (c) the preliminarily polymerized ethylene polymer has an intrinsic viscosity [ eta ] of 0.5 dl/g to 2.5 dl/g as measured in tetralin at 135 DEG C.; and B) an organoaluminum compound. Thus, an olefin polymer small in the extent of adhesion to polymerization reactor, small in the number of fish-eyes, low in the content of fine powder, high in bulk density and good in fluidity could be produced.
申请公布号 US5463000(A) 申请公布日期 1995.10.31
申请号 US19920966850 申请日期 1992.10.27
申请人 SUMITOMO CHEMICAL COMPANY, LIMITED 发明人 MIYOSHI, YOSHIHIRO;SHIRAISHI, HIROYUKI;KAWAI, KIYOSHI;KOGA, HIDEAKI
分类号 C08F2/34;C08F4/60;C08F4/658;C08F10/00;(IPC1-7):C08F4/656 主分类号 C08F2/34
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