发明名称 Liquification of trans, trans-4,4'-diisocyanate dicyclohexylmethane by partially reacting the isocyanate groups with blocking agents
摘要 The present invention relates to a liquid, storage-stable isocyanate having a viscosity of less than 100,000 mPa.s at 23 DEG C. and an isocyanate content of from about 9 to 20% by weight, and is prepared by reacting a solid 4,4'-methylene bis(cyclohexyl isocyanate) with a blocking agent. The 4,4'-methylene bis(cyclohexyl isocyanate) must contain at least 35 to 100% by weight of the trans,trans isomer. More generally, this liquid isocyanate is prepared by reacting the solid or semi-solid 4,4'-methylene bis (cyclohexyl isocyanate) with the blocking agent in quantities such that at least 22% but less than 60% of the isocyanate groups are blocked. Preferred blocking agents are the ketoximes, and mixtures thereof.
申请公布号 US5455374(A) 申请公布日期 1995.10.03
申请号 US19930085234 申请日期 1993.06.30
申请人 BAYER CORPORATION 发明人 SENEKER, STEPHEN D.;KANE, SCOTT A.
分类号 C07C263/18;(IPC1-7):C07C249/00 主分类号 C07C263/18
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