摘要 |
A nonaqueous electrolyte secondary battery having an enhanced capacity and a long charge/discharge cycle life is disclosed. The nonaqueous electrolyte secondary battery comprises a positive electrode housed in a case and containing a chalcogen compound as an active material, a negativs electrode arranged in the case such that a separator is sandwiched between the positive and negative electrodes and containing a carbonaceous material as an active material that absorbs and dischargss lithium ions and a nonaqueous electrolyte contained in the case and prepared by dissolving 0.5 mol/? to 1.5 mol/? of electrolytic salt selected from the group consisting of LiPF6, LiBF4, LiAsF6 and LiCF3SO3 in a solvent mixture comprising at least one first nonaqueous solvent selected from the group consisting of noncyclic carbonate, cyclic carbonate, .gamma.-butylolactone and acetonitrile and at least one second nonaqueous solvent containing selected from the group consisting of 1,2-diethoxyethane, 1,2-dimethoxyethane, 1,2-ethoxymethoxyethane, 1,3-dimethoxypropane, diethylether and tetrahydrofurane, the amount of the second nonaqueous solvent in the solvent mixture being so determined that the mol ratio (¢S!/¢Li!) of the second nonaqueous solvent ¢S! to lithium ions ¢Li! is 0.5 to 3. |
申请人 |
KABUSHIKI KAISHA TOSHIBA;TOSHIBA BATTERY CO., LTD. |
发明人 |
TAKAMI, NORIO;OHSAKI, TAKAHISA;KURISU, NORIHITO;INADA, KUNIAKI |