摘要 |
The present invention concerns polymers of unsaturated saccharides and their derivatives which contain a double bond in the ring (endo-cyclic) or on the ring (exo-cyclic). It further concerns copolymers having ethylenically unsaturated compounds. The unsaturated saccharides are ethylenically unsaturated monosaccharides, disaccharides or oligosaccharides which contain a double bond in the ring (endo-cyclic) or on the ring (exo-cyclic), chemically protected or unprotected, enzymatically or chemically modified unsaturated mono, di or oligosaccharides or mixtures of said compounds. The ethylenically unsaturated compounds are selected from the group containing: (a) monoethylenically unsaturated C3 - C10 carboxylic acids and their alkali metal, alkaline earth metal or ammonium salts; (b) monoethylenically unsaturated C3 - C12 carboxylic acid esters; (c) acrylic or methacrylic acid dialkylaminoalkyl esters with a total of up to 30 carbon atoms in the dialkylaminoalkyl residue and which may be present in the N-quaternary or salt form; (d) acrylic acid amides, methacrylic acid amide, N-(dialkyl)-acrylic or methacrylic acid amide; (e) N-vinylimidazoles which may be substituted on the heterocyclic ring by up to three C1 - C12 alkyl residues and may be present in the N-quaternary or salt form; (f) five to eight-member N-vinyllactams which may be substituted on the ring by up to three C1 - C12 alkyl residues; (g) maleic acid anhydride, maleic acid dialkyl ester which may be present with a total of up to two carbon atoms in the alkyl residue; (h) styrene which may be substituted on the aromatic ring by up to two C1-C3 alkyl residues; (i) acrylnitrile, methacrylnitrile; and (j) N-vinylpyridines which may be substituted on the heterocyclic ring by up to four C1- C12 alkyl residues and may be present in the N-quaternary or salt form.
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申请人 |
BUCHHOLZ, KLAUS, PROF. DR., 38124 BRAUNSCHWEIG, DE;VEREIN DER ZUCKERINDUSTRIE, 53113 BONN, DE |
发明人 |
BUCHHOLZ, KLAUS, DR., 38124 BRAUNSCHWEIG, DE;YAACOUB, EMILE, DR., 38159 VECHELDE, DE;WARN, SUSANNE, 38106 BRAUNSCHWEIG, DE;SKERIES, BERNHARD, 38108 BRAUNSCHWEIG, DE;WICK, STEFAN, 21614 BUXDEHUDE, DE;BOEKER, MATHIAS, 38102 BRAUNSCHWEIG, DE |