| 摘要 |
<p>Polyether-polyurethane-polyureas are prepared by intimately mixing a polyether-polyurethane, prepared by reaction of at least one polyether polyol with a stoichiometric excess of a polyisocyanate in a ratio of NCO:OH of 1.5-3.0:1, and having a viscosity of 4000-20,000 centipoises at 25 DEG C., with a diamine in an inert volatile solvent, in proportions such that the ratio of NH2:OH>0.5:1 and NC:(OH+NH2) is 0.95-1.6:1, these ratios being calculated on the basis of the polyol, polyisocyanate and diamine starting materials. Suitable polyether polyols are polyethylene- and polypropylene-glycols and ethoxylated or propoxylated trimethylolpropane, glycerol, hexane triol or pentaerythritol, mixtures having M.W. 400-4000 on average are preferred. Suitable polyisocyanates are toluene diisocyanate and diphenylmethane diisocyanate. Suitable diamines are benzidine, 3:31-dichlorobenzidine, 3:31 - dichlorodiphenylmethane diamine, diphenylmethane diamine, o,o1-dinitrobenzidine, 2-methylpiperazine, hexamethylene diamine, and o-toluidine. Suitable solvents include acetone, MEK, methylene dichloride, ethylene dichloride, methyl acetate, ethyl acetate, ethylene glycol methyl- or ethyl-ether acetates, DMSO, DMF, DMA, propylene carbonate and THF. The prepolymer and the diamine may be mixed by simultaneous spraying on to a surface, with the prepolymer at 5-100 DEG C. Pigments may be added to the diamine solution. In Examples prepolymers are prepared from toluene diiso cyanate and various polypropylene or polyethylene glycols, and/or propoxylated- or ethoxylated- and propoxylated-trimethylolpropane or -glycerol or -pentaerythritol or -ethylenediamine, or, in part, trimethylolpropane. These are sprayed on to surfaces simultaneously with solutions in acetate and/or ketone solvents of p,p1-diamino-diphenylmethane or m-phenylene diamine, or solutions of each of the above listed suitable diamines in suitable solvents.ALSO:Surfaces, e.g. roofing, floors, concrete walls and terraces, may be coated with a polyurethane by simultaneously spraying thereon a liquid polyurethane prepolymer and a solution of a diamine, (Ex 6). The prepolymer has a viscosity of 4,000-20,000 centipoises at 25 DEG C and is prepared by reacting a polyether polyol with a polyisocyanate in proportions providing a ratio of NCO:OH groups of 1.5-3.0:1. The final polyurethane has ratios of NCO:(OH + NH2)=0.95-1.6:1 and NH2:OH>0.5:1, calculated on the basis of the polyol, polyisocyanate and diamine starting materials. A wooden board, metal plate, foamed sheet, e.g. expanded polyurethane, felt, leather or fabric may be coated with the polyurethane by transfer from a siliconized support which may have a grained surface, to produce for example a footwear sole, carpet for the automobile industry, decorative wall or floor coverings.</p> |
