发明名称 REGENERATING METHOD OF RUTHENIUM CATALYST
摘要 <p>PURPOSE:To regenerate and reuse a silica carrying ruthenium catalyst degradated in activity by hydrogenation treatment by treating the silica carrying ruthenium catalyst successively with gaseous oxygen and next, gaseous hydrogen. CONSTITUTION:The silica carrying ruthenium catalyst is used for the hydrogenation reaction of a carbonyl compound, the hydrogenation reaction of carbon monoxide or the like. And the silica carrying ruthenium catalyst degradated in activity is heat-treated, at first, at >=60 deg.C, preferably 90-300 deg.C and further preferably 150-200 deg.C, in an oxygen containing gas and next, at usually 20-200 deg.C, preferably 50-200 deg.C, in a hydrogen containing gas. Thus, the silica carrying ruthenium catalyst is efficiently regenerated.</p>
申请公布号 JPH07178341(A) 申请公布日期 1995.07.18
申请号 JP19930328458 申请日期 1993.12.24
申请人 MITSUBISHI CHEM CORP 发明人 MURAI NOBUYUKI;IWASAKA YOUJI;NISHIMURA SEIJIRO
分类号 B01J23/96;B01J38/18;C07C29/136;C07C31/00;(IPC1-7):B01J23/96 主分类号 B01J23/96
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