发明名称 |
Alumimum trichloride catalyzed hydrogenation of high-boiling residue from direct process |
摘要 |
A process for the production of monosilanes from the high-boiling residue resulting from the reaction of organohalides with silicon metalloid in a process typically referred to as the "direct process." The present process comprises forming a mixture comprising an organotrihalosilane and the high-boiling residue in the presence of hydrogen gas and a catalytic amount of aluminum trichloride. The present process results in consumption of the organotrihalosilane rather than a net increase which typically occurs in processes for hydrogenation of the high-boiling residue. At least a portion of the catalytic amount of aluminum trichloride may be formed in situ during conduct of the direct process and isolation of the high-boiling residue.
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申请公布号 |
US5430168(A) |
申请公布日期 |
1995.07.04 |
申请号 |
US19940329758 |
申请日期 |
1994.10.27 |
申请人 |
DOW CORNING CORPORATION |
发明人 |
FERGUSON, STEPHEN P.;JARVIS, JR., ROBERT F.;NAASZ, BRIAN M.;OLTMANNS, KIMBERLY K.;WARRICK, GORDON L.;WHITELEY, DARREL L. |
分类号 |
B01J27/10;C07B61/00;C07F7/08;C07F7/12;(IPC1-7):C07F7/08 |
主分类号 |
B01J27/10 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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