摘要 |
New herbicidal substd. bicycloheptandione derivs. of formula (I) are prepd. by ring-closure reaction of cpds. (II) in the presence of a base. R1 = lower alkyl, opt. substd. phenyl, opt. substd. aralkyl or opt. substd. heterocyclic; R2 = halo, alkoxy, alkylthio, alkylsulphonyl, alkyl, alkoxyalkyl or alkoxycarbonyl; n = 0-4; R3 and R4 = H or lower alkyl; and Q = a leaving gp. Pref. cpd. (II), (where Q = halo, alkylsulphonate or phenylsulphonate), is treated with 2 moles (or excess) base at pref. 0-50 deg.C for 0.5-10h in a solvent (e.g. water, an alcohol, CH2Cl2, benzene, toluene, EtOAc, DMF, THF, CH3CN etc). The base is e.g. an alkali or alkaline earth hydroxide, a trialkylamine, pyridine, DBU, t-BuOK etc. |
申请人 |
NIPPON SODA CO. LTD., TOKIO/TOKYO, JP |
发明人 |
UEDA, AKIYOSHI ODAWARA RESEARCH CENTER, TAKADA, ODAWARA-SHI KANAGAWA, JP;SUGA, SHIGEMI TAKAOKA PLANT NIPPON SODA CO., LTD., TAKAOKA-SHI TOYAMA, JP;ADACHI, HIROYUKI ODAWARA RESEARCH CENTER NIPPON, TAKADA, ODAWARA-SHI KANAGAWA, JP;AIHARA, TOSHIO ODAWARA RESEARCH CENTER NIPPON, TAKADA, ODAWARA-SHI KANAGAWA, JP;TOMIDA, KAZUYUKI ODAWARA RESEARCH CENTER NIPPON, TAKADA, ODAWARA-SHI KANAGAWA, JP;YAMAGISHI, HIDEKI ODAWARA RESEARCH CENTER NIPPON, TAKADA, ODAWARA-SHI KANAGAWA, JP;HOSAKA, HIDEO ODAWARA RESEARCH CENTER NIPPO, TAKADA, ODAWARA-SHI KANAGAWA, JP |