发明名称 Process for producing grafted polycarbonate resin
摘要 Disclosed is a process for producing a grafted polycarbonate resin for optical use, which comprises adding to an aqueous suspension of an aromatic polycarbonate resin having radical-polymerizable unsaturated terminal group on a molecule wherein the aromatic polycarbonate resin has an average particle diameter of 0.1 to 5 mm and an apparent density of 0.2 to 0.9 g/cm3, a vinyl monomer and a radical-polymerization initiator, heating the aqueous suspension at a lower temperature by 5 DEG C. to 20 DEG C. than the decomposition temperature for a half-life period of 10 hours of the radical-polymerization initiator, thereby impregnating the polycarbonate resin with the vinyl monomer and the radical-polymerization initiator, then elevating the temperature to the range of from a lower temperature by 50 DEG C. to a higher temperature by 30 DEG C. than the decomposition temperature for a half-life period of 10 hours of the radical-polymerization initiator, thereby conducting a graft-polymerization reaction to obtain 90% by weight or more of conversion of vinyl monomer.
申请公布号 US5426159(A) 申请公布日期 1995.06.20
申请号 US19930091756 申请日期 1993.07.15
申请人 MITSUBISHI GAS CHEMICAL COMPANY, INC. 发明人 UMEMURA, TOSHIKAZU
分类号 C08F290/06;(IPC1-7):C08F283/02;C08L69/00 主分类号 C08F290/06
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