发明名称 Halogen-free blowing agents that include cycloaliphatic hydrocarbons and are suitable for isocyanate-based polymeric foams.
摘要 <p>The mfr. uses a halogen-free organic liq. as a physical blowing agent for the foam. The organic liq. contains a positive azeotrope of min. b.pt. 15-80 deg.C at normal atmospheric pressure and comprises (a) a 5-7C cycloaliphatic hydrocarbon, and (b) a 4C aliphatic ether, a 2-5C aliphatic carboxylic acid ester, a 4C aliphatic ketone or a mixt. 1-10 pts. wt. of a nucleating agent per 100 pts. wt. of foaming ingredients are present during foaming pref. perfluoropentane. The wt. ratio of azeotrope components in the organic liq. is within +/- 20% (+/- 10%) of an ideal azeotrope compsn. The foam is pref. a rigid polyurethane, integral skin flexible polyurethane or urethane-modified polyisocyanurate foam. The azeotrope has a min. boiling temp. of pref. 15-45 (20-40) deg.C. It comprises cyclopentane and (m)ethyl formate or methyl acetate, cyclohexane and methyl formate, cyclohexane or cyclohexene and 2-butanone, cyclopentane or cyclopentene and 2-butanone or cyclopentane and furan.</p>
申请公布号 EP0657495(A1) 申请公布日期 1995.06.14
申请号 EP19940119248 申请日期 1994.12.06
申请人 NISSHINBO INDUSTRIES, INC. 发明人 ASHIDA, KANEYOSHI
分类号 C08J9/14;C09K3/00;(IPC1-7):C08J9/14;C08J9/00 主分类号 C08J9/14
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