发明名称 |
Verfahren zur kontinuierlichen Herstellung von 2,2,6,6-letramethylpiperidin |
摘要 |
The reduction of triacetonamine with hydrazine also proceeds continuously by means of a reactive distillation if the hydrazone is first formed and this is continuously transported at the bottom of a distillation column into the distillation bottom, which consists of a high-boiling solvent and an alkali, and the resulting 2,2,6,6-tetramethylpiperidine is distilled off as an azeotrope. In this procedure, a hydrazine/triacetonamine ratio of 1.5 : 1 to 2.0 : 1 is sufficient, it being possible distinctly to increase the product yield (> 90%) compared with the conventional synthesis. Additionally, the amounts of alkali and solvents used can be distinctly reduced. |
申请公布号 |
DE4342276(A1) |
申请公布日期 |
1995.06.14 |
申请号 |
DE19934342276 |
申请日期 |
1993.12.11 |
申请人 |
HOECHST AG, 65929 FRANKFURT, DE |
发明人 |
KAMPMANN, DETLEF, DR., 86368 GERSTHOFEN, DE;STUHLMUELLER, GEORG, 86456 GABLINGEN, DE |
分类号 |
C07D211/12;C07D295/023 |
主分类号 |
C07D211/12 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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