| 摘要 |
A process for the production of olefins and diolefins, such as 1,3-butadiene, comprising contacting an aliphatic hydrocarbon, such as butane, with a heterogeneous catalyst composition containing reactive oxygen under reaction conditions such that a more highly unsaturated aliphatic hydrocarbon is selectively formed in a high productivity. The catalyst is a composition comprising a catalyst component of magnesia, an oxide of molybdenum, a Group IA metal oxide promoter, and optionally vanadium oxide. In a preferred embodiment, the catalyst composition also comprises a support component of magnesium and alumina and/or magnesium aluminate spinel. The present catalyst has high surface area and high attrition resistance. |
