发明名称 |
Oxidzusammensetzungen mit grosser Oberfläche und deren Verwendung in der Konversion von niedrigen Kohlwasserstoffen. |
摘要 |
Processes for the conversion of hydrocarbons, and most preferably methane, to higher hydrocarbons and olefins are disclosed, including contacting the hydrocarbons with a mixed metal oxide catalyst having the pyrochlore structure. Preferably, these catalysts have the general formula AnB2O7-x, where A can be various mono-, di-, and trivalent metal cations, B can be various tri-, tetra-, penta-, and hexavalent metal cations, O </= n </=2.0, and O </= x </= 1.0. Novel, high surface area, mixed metal oxide catalysts having the pyrochlore structure are also disclosed, including those having the formula A2B2O7, where A is divalent and B is niobium and/or tantalum, and those having the formula A2(Sn2-yAy)O7-z, where A is bismuth and/or lead, O.O </= y </= 1.0,and O.O </= z </= 1.0. |
申请公布号 |
DE69016853(D1) |
申请公布日期 |
1995.03.23 |
申请号 |
DE1990616853 |
申请日期 |
1990.06.25 |
申请人 |
EXXON RESEARCH AND ENGINEERING CO., FLORHAM PARK, N.J., US |
发明人 |
JACOBSON, ALLAN JOSEPH, PRINCETON,NEW JERSEY 08540, US;HALL, RICHARD BARRY, WHITEHOUSE STATION, NEW JERSEY, US;MIMS, CHARLES ARTHUR, KITCHENER, ONTARIO, CA;LEWANDOWSKI, JOSEPH THADDEUS, WHITEHOUSE STATION, NJ 08889, US |
分类号 |
B01J23/00;C01G19/00;C01G29/00;C01G33/00;C01G35/00;C01G41/00;C01G55/00;C07C2/84 |
主分类号 |
B01J23/00 |
代理机构 |
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地址 |
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