发明名称 Oxidzusammensetzungen mit grosser Oberfläche und deren Verwendung in der Konversion von niedrigen Kohlwasserstoffen.
摘要 Processes for the conversion of hydrocarbons, and most preferably methane, to higher hydrocarbons and olefins are disclosed, including contacting the hydrocarbons with a mixed metal oxide catalyst having the pyrochlore structure. Preferably, these catalysts have the general formula AnB2O7-x, where A can be various mono-, di-, and trivalent metal cations, B can be various tri-, tetra-, penta-, and hexavalent metal cations, O </= n </=2.0, and O </= x </= 1.0. Novel, high surface area, mixed metal oxide catalysts having the pyrochlore structure are also disclosed, including those having the formula A2B2O7, where A is divalent and B is niobium and/or tantalum, and those having the formula A2(Sn2-yAy)O7-z, where A is bismuth and/or lead, O.O </= y </= 1.0,and O.O </= z </= 1.0.
申请公布号 DE69016853(D1) 申请公布日期 1995.03.23
申请号 DE1990616853 申请日期 1990.06.25
申请人 EXXON RESEARCH AND ENGINEERING CO., FLORHAM PARK, N.J., US 发明人 JACOBSON, ALLAN JOSEPH, PRINCETON,NEW JERSEY 08540, US;HALL, RICHARD BARRY, WHITEHOUSE STATION, NEW JERSEY, US;MIMS, CHARLES ARTHUR, KITCHENER, ONTARIO, CA;LEWANDOWSKI, JOSEPH THADDEUS, WHITEHOUSE STATION, NJ 08889, US
分类号 B01J23/00;C01G19/00;C01G29/00;C01G33/00;C01G35/00;C01G41/00;C01G55/00;C07C2/84 主分类号 B01J23/00
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