Inhibition of dioxane formation during recovery of glycols from polyester resins

摘要

There is described a process for avoiding dioxane formation during the depolymerization of polyester into glycol and ester components by passing superheated methanol through a reaction mixture containing polyester, oligomer and contaminants that are capable of forming sulfuric or halogen acids, the process comprising the step of adding sufficient base to neutralize any acid formed from the contaminants.