发明名称 PROCESS FOR THE PREPARATION OF O-SUBSTITUTED HYDROXYLAMMONIUM SALTS
摘要 In order to prepare O-substituted hydroxylammonium salts having formula (I): R1-CHX-O-NH2 . HL, in which L = halogen, hydrogen sulphate; X = H, alkyl R1 = possibly substituted phenyl, thienyl, furanyl, pyrrolyl or -CR2=CR3R4, in which R2, R3, R4 = H, halogen or alkyl, an acetonoxime-O-alkyl or acetonoxime-O-benzyl ether having formula (II) is reacted with water and a mineral acid H-L while the resulting acetone is continuously removed, and hydrolysis is intermittently carried out at 0-50 .degree.C and under 10-500 mbar pressure. The O-substituted hydroxylammonium salts having the formula (I) are intermediate products for plant protective agents and pharmaceuticals.
申请公布号 CA2168457(A1) 申请公布日期 1995.02.09
申请号 CA19942168457 申请日期 1994.07.08
申请人 BASF AKTIENGESELLSCHAFT 发明人 KLEIN, ULRICH;BUSCHMANN, ERNST;KEIL, MICHAEL;GOETZ, NORBERT;HARREUS, ALBRECHT
分类号 C07C239/20;(IPC1-7):C07C239/20;C07D207/335;C07D307/52;C07D333/20 主分类号 C07C239/20
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