发明名称 METHOD FOR ISOMERIZING ALDOSE STRUCTURE-HAVING COMPOUND INTO KETOSE STRUCTURE-HAVING COMPOUND, ISOMERIZATION AND ACCELERATING AGENT THEREOF
摘要 PURPOSE:To isomerize an aldose structure-having compound into a ketose structure-having compound in the presence of an organic germanium compound having a specific partial structure without requiring a special installation and a troublesome operation by eliminating the technical difficulties of the prior art. CONSTITUTION:The isomerization method comprises isomerizing (B) the aldose structure-having compound into (C) the ketose structure-having compound with (A) an organic germanium compound having a partial structure of formula I, preferably in the presence of the component A. The component A and the component B are preferably a compound of formula II or III [R1-R3, R4-R6 are H, lover alkyl, (substituted)phenyl. (protected)amino; X1, X2 are OH, O-lower alkyl, amino, OY1, OY2, (Y1, Y2 are metal, compound having a basic group); n is >=1] and glucose, respectively, and the isomerization is preferably the isomerization of the glucose into fructose.
申请公布号 JPH0717991(A) 申请公布日期 1995.01.20
申请号 JP19930188877 申请日期 1993.06.30
申请人 NATL FOOD RES INST;ASAI GERUMANIUMU KENKYUSHO:KK 发明人 KAKIMOTO NORIHIRO;UMEDA KEIJI;HARUMI TAKAFUMI
分类号 B01J31/02;C07B61/00;C07H1/00;C07H3/02;C07H3/04;C07H3/06;C08B37/00 主分类号 B01J31/02
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