| 摘要 |
chemistry of polymers. SUBSTANCE: described is new fluorinated thermoplastic elastomer having block structure consisting of at least one segment of type A fluorinated polymer which has plastic properties and at least segment of type B fluorinated polymer which has plastic properties. At least one type A or type B segment comprises monomer units based on iodinated olefin of formula: CX2=CX-Rf-CHR-I,(l) wherein X is H, F or CH3: R is H or -CH3; Rf is perfluoroalkylene radical, linear or branched, optionally containing one or more oxygen atoms of ether, or (per)fluoropolyoxyalylene radical. Described are elastomers and method of preparation thereof. EFFECT: improved physico-mechanical and elastic properties of the desired product. 21 cl, 4 ex, 2 tbl |
