发明名称 alpha -methylenecyclopentanone derivative and process for producing the same
摘要 Disclosed herein is an alpha -methylene-cyclopentanone derivative represented by the formula [I] below which is useful as an intermediate for pharmaceuticals and insecticides, especially prostaglandins. Also disclosed herein is a process for producing the derivative advantageously on an industrial scale. <IMAGE> [I] where X denotes ( alpha -OZ, beta -H) or ( alpha -H, beta -OZ), with Z representing a protecting group for the hydroxyl group; U denotes ( alpha -H, beta -R1) or ( beta -R1, alpha -H); R1 denotes <IMAGE> where R2 denotes a protected hydroxyl group, a substituted or unsubstituted C1-15 alkyl group, a substituted or unsubstituted C2-15 alkenyl group, a substituted or unsubstituted C2-15 alkynyl group, or a substituted or unsubstituted C6-15 aryl group; Z' denotes a protecting group for the hydroxyl group; and k is 0 or 1).
申请公布号 US5380900(A) 申请公布日期 1995.01.10
申请号 US19920834348 申请日期 1992.02.12
申请人 NISSAN CHEMICAL INDUSTRIES, LIMITED 发明人 SATO, FUMIE;ARAI, KAZUTAKA;MIYAJI, KATSUAKI
分类号 C07C45/61;C07C49/707;C07C405/00;C07F7/18;(IPC1-7):C07F7/08;C07F7/10 主分类号 C07C45/61
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