发明名称 PRODUCTION OF ESTERS
摘要 <p>PURPOSE:To extremely efficiently obtain the subject compound useful as a perfume, a freezer oil, etc., at a low temperature in a short time and at a low cost by reacting an olefin, carbon monoxide and an alcohol in the presence of hydrogen fluoride. CONSTITUTION:An olefin (e.g. propylene or butylene), carbon monoxide and an alcohol (e.g. methanol or ethanol) are reacted with each other in the presence of hydrogen fluoride. Preferably, the olefin is reacted with carbon monoxide in the hydrogen fluoride at 20-50 deg.C under a pressure of 10-80kg/cm<2>G and subsequently with the alcohol at 0-50 deg.C. The hydrogen fluoride and the alcohol are preferably used in amounts of 7-15 moles and 0.7-1.5 moles, respectively, per mole of the olefin.</p>
申请公布号 JPH06345688(A) 申请公布日期 1994.12.20
申请号 JP19930143679 申请日期 1993.06.15
申请人 MITSUBISHI GAS CHEM CO INC 发明人 TAKEFUMI TADAYOSHI;SHIOKAWA YOSHIHIRO;MATSUMOTO SHUNICHI
分类号 B01J27/12;C07B61/00;C07C67/38;C07C69/24;C07C69/30 主分类号 B01J27/12
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