| 摘要 |
FIELD: chemistry.SUBSTANCE: present invention relates to organic chemistry, namely to a method for producing N-arylaziridinumfullerene, which can be used as complexing agents, sorbents, biologically active compounds, as well as for creating new materials with given properties. Method involves reaction of fullerene Cwith arylaziridinums RN(where R = Ph, 4-Cl-Ph 2-NO-Ph 2-MeO-Ph, Naph) in the presence of lanthanum La (OTf), taken in the molar ratio C: RN: La (OTf)= 1: (0.5-2):(0.5-2), at the temperature of 80 °C, in chlorobenzene for 1-3 hours.EFFECT: obtaining N-arylaziridinum [2′,3′: 1,9]fullerene [60] (1) with the output of 20-50 %.1 cl, 1 tbl, 1 ex |
