ETHYLENE GLYCOL RECOVERY PROCESS

摘要

The present invention is an improved process for the recovery of ethylene glycol from spent glycol generated in the manufacture of polyethylene terephthalate. The spent glycol typically consists of metal oxide catalyst residues, low molecular weight terephthalate oligomers, diethylene glycol and other trace impurities. The improved process of the present invention is based on the principle that elevating the temperature of the spent glycol increases the solubility of the low molecular weight oligomers so that the low molecular weight oligomers can be dissolved in the ethylene glycol and further that the spent glycol at an elevated temperature may be passed through filters (5), activated carbon (6), and an ion exchange bed of cations (7), anions (8) and mixed resins (9) to remove metal oxide catalysts, color forming impurities and other trace impurities.