发明名称 |
Process for the preparation of predominantly unbranched higher primary alcohols. |
摘要 |
To prepare higher, predominantly unbranched primary alcohols, olefins obtained in a Fischer-Tropsch synthesis are reacted with hydrogen and carbon monoxide in the presence of water and also rhodium in metallic form or in the form of a compound and in the presence of a water-soluble phosphine as catalyst. The reaction product obtained is hydrogenated. The water-soluble phosphines employed are compounds whose anion is a phosphine containing at least one sulphonated or carboxylated aromatic radical and whose cation is a quaternary ammonium or phosphonium ion. |
申请公布号 |
ZA9309292(B) |
申请公布日期 |
1994.08.04 |
申请号 |
ZA19930009292 |
申请日期 |
1993.12.10 |
申请人 |
HOECHST AKTIENGESELLSCHAFT |
发明人 |
HELMUT BAHRMANN;WOLFGANG GREB;PETER LAPPE;JUERGEN SZAMEITAT;GREGOR DECKERS;PETER HEYMANNS;THOMAS MUELLER;ERNST WIEBUS |
分类号 |
B01J31/24;C07B61/00;C07C29/141;C07C29/158;C07C29/16;C07C31/125;C07C45/50;C23C14/16 |
主分类号 |
B01J31/24 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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