发明名称 |
Process for preparing 2,5-diphenylterephthalic acid by oxidation |
摘要 |
Provided is a process for preparing 2,5-diphenylterephthalic acid, which is useful in preparing certain polyesters, especially liquid-crystalline polyesters. In this process, p-xylene is di-alkylated with cyclohexene to provide 2,5-dicyclo-hexyl-p-xylene, which is in turn dehydrogenated to provide 2,5-diphenylxylene. 2,5-Diphenylxylene is then oxidized to provide 2,5-diphenylterephthalic acid by utilization of a cobaltous/manganous/bromide oxidation system.
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申请公布号 |
US5334754(A) |
申请公布日期 |
1994.08.02 |
申请号 |
US19920930890 |
申请日期 |
1992.08.14 |
申请人 |
EASTMAN CHEMICAL COMPANY |
发明人 |
SUMNER, JR., CHARLES E.;GUSTAFSON, BRUCE L.;ARNOLD, III, ERNEST W.;FUGATE, ERIC J.;FULLER, JR., DEWEY W. |
分类号 |
B01J27/128;B01J29/08;B01J31/04;C07C51/265;C07C63/26;(IPC1-7):C07C51/215;C07C67/39 |
主分类号 |
B01J27/128 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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