发明名称 |
ETHYLENE/.ALPHA.-OLEFIN COPOLYMER COMPOSITION, GRAFT MODIFIED ETHYLENE/.ALPHA.-OLEFIN COPOLYMER COMPOSITION, ETHYLENE COPOLYMER COMPOSITION, AND MULTI-STAGE OLEFIN POLYMERIZATION PROCESS |
摘要 |
An ethylene/.alpha.-olefin copolymer composition comprising an ethylene/.alpha.-olefin copolymer and another ethylene/.alpha.olefin copolymer ¢B1!. The former ethylene/.alpha.-olefin copolymer can be prepared in the presence of a catalyst for olefin polymerization containing an organoaluminum oxycompound (a) and at least two kinds of specific metallocene compounds (b), and the latter ethylene/.alpha.-olefin copolymer ¢B1! can be prepared in the presence of a catalyst for olefin polymerization containing an organoaluminum oxycompound (a) and a specific metallocene compound (b'). A graft modified ethylene/.alpha.-olefin copolymer composition obtained by graft copolymerizing an ethylene/.alpha.olefin copolymer composition with a polar monomer. The ethylene/.alpha.-olef1n copolymer composition comprises an ethylene/.alpha.-olefin copolymer prepared in the presence of a catalyst for olefin polymerization containing an organoaluminum oxy-compound (a) and a specific metallocene compound (b'), and the above ethylene/.alpha.-olefin copolymer ¢B1!. An ethylene copolymer composition comprising the above-mentioned graft modified ethylene/.alpha.-olefin copolymer composition and polyolefin. A multi-stage olefin polymerization process comprising a stage of preparing an ethylene/.alpha.-olefin copolymer ¢A1! in the presence of a catalyst for olefin polymerization containing an organoaluminum oxy-compound (a), a specific metallocene compound (b-I) and a specific metallocene compound (b-II) and a stage of preparing an ethylene/.alpha.olefin copolymer ¢B1! in a different polymerizer from that for the copolymerization reaction of the above stage in the presence of a catalyst for olefin polymerization containing an organoaluminum oxy-compound (a) and a specific metallocene compound (b'). The ethylene/.alpha.-olefin copolymer composition of the invention is excellent in heat stability and moldability. From this composition, a film of high transparency, high mechanical strength and high blocking resistance can be produced. The graft modified ethylene/.alpha.-olefin copolymer composition of the invention is excellent in moldability. From this composition, a film having high transparency and good adhesion to highly polar materials can be produced. The ethylene copolymer composition of the invention is excellent in moldability. From this composition, a film having high transparency and good adhesion to highly polar materials can be produced. The multi-stage olefin polymerization process of the invention can prepare an ethylene/.alpha.-olefin copolymer composition of good heat stability and moldability from which a film of high transparency and high mechanical strength can be produced.
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申请公布号 |
CA2103380(A1) |
申请公布日期 |
1994.05.20 |
申请号 |
CA19932103380 |
申请日期 |
1993.11.18 |
申请人 |
MITSUI PETROCHEMICAL INDUSTRIES, LTD. |
发明人 |
TSUTSUI, TOSHIYUKI;YOSHITSUGU, KEN;TAKAHASHI, MAMORU;TODO, AKIRA;OHTA, SEIJI;INAGAKI, HAJIME |
分类号 |
C08F4/659;C08F4/6592;C08F10/00;C08F210/16;C08F255/02;C08F255/04;C08F255/08;C08F287/00;C08F297/08;C08L23/04;C08L23/08;C08L51/06;(IPC1-7):C08L23/08 |
主分类号 |
C08F4/659 |
代理机构 |
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代理人 |
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