发明名称 |
PROCEDEU DE PREPARARE A UNOR DINITROANILINE CU ACTIUNE ERBICIDA |
摘要 |
<p>Prepn. of herbicidal cpds. of formula (I) (where Y is 1-4C alkyl, halogen CF3; Z is H, halogen; 1-4C alkyl opt. substd. by one halogen or 1-4C alkoxy; 1-4C alkoxy; Ra is 1-6C alkyl, 4-6C cycloalkyl, 1-4C alkoxy - 1-4C alkyl; Rb is H or one of the values of Ra) comprises nitration of the corresp. N-alkylanilines with a mixed acid within the limits 60% HNO3 8% H2SO4, 32% H2O; 50% HNO3, 35% H2SO4, 15% H2O; 2% HNO3, 68% H2SO4, 30% H2O; 2% HNO3, 20% H2SO4, 70% H2O AT 0-70 degrees C. The process avoids the need to block the amino gp. by acylation when Rb is H. This is overcome by denitrosation of the by-prod. N-nitroso cpd. by treating it with HC1 and sulphamic acid.</p> |
申请公布号 |
RO70074(A) |
申请公布日期 |
1980.06.15 |
申请号 |
RO19740079298 |
申请日期 |
1974.06.25 |
申请人 |
AMERICAN CYANAMID CO.,US |
发明人 |
LEVY,STEPHEN D.,US;DIEHL,ROBERT E.,US;GASTROCK,WILLIAM H.,US;ROSS,LAWRENCE J.,US |
分类号 |
A01N33/18;C07B31/00;C07B43/02;C07B61/00;C07C67/00;C07C209/00;C07C209/42;C07C211/48;C07C211/52;C07C213/00;C07C217/08;C07C217/76;C07C217/84;C07C313/00;C07C315/04;C07C317/36;(IPC1-7):07C87/52 |
主分类号 |
A01N33/18 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|