发明名称 CATALYST FOR OLEFIN POLYMERIZATION AND METHOD OF POLYMERIZING OLEFIN USING THE SAME
摘要 PURPOSE:To obtain the catalyst which gives an olefin polymer having excellent particle properties and has high catalytic activity and excellent particle proper ties by constituting it of an organoaluminumoxy compound, a specific transition metal compound, and an organoaluminum hydride. CONSTITUTION:The catalyst comprises (b) an organoaluminumoxy compound (e.g. methylaluminoxane), (a) a compound of a Group IVB transition metal of the Periodic Table which compound contains a ligand having a cyclopentadienyl skeleton [e.g. bis(1-methyl-3-n-butylcyclopentadienyl)zirconium dichloride], and (c) an organoaluminum hydride (e.g. diisobutylaluminum hydride). It may contain (d) a carrier in fine powder form (e.g. silica). According to need, it may further contain (g) an olefin prepolymer as a catalytic component obtained by prepolymerizing an olefin in the presence of (e) an organic Al compound and/or an organoaluminum hydride, and furthermore contain (f) an organic Al compound. The process for catalyst preparation is shown in the drawing.
申请公布号 JPH06100614(A) 申请公布日期 1994.04.12
申请号 JP19930171256 申请日期 1993.06.17
申请人 MITSUI PETROCHEM IND LTD 发明人 OONO TATSUMASA;TSUTSUI TOSHIYUKI
分类号 C08F4/655;C08F4/60;C08F4/602;C08F4/656;C08F4/659;C08F4/6592;C08F10/00;(IPC1-7):C08F4/655 主分类号 C08F4/655
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