发明名称 Method for the preparation of a polymeric shaped article containing an electrically conductive polymer.
摘要 The invention relates to a method for the preparation of a polymeric shaped article containing an electrically conductive polymer, wherein a base shaped article containing a matrix polymer is contacted with an anode in the presence of an electrolyte-containing medium containing monomer units, which on polymerisation to form an electrically conductive polymer, and wherein a voltage is applied between the anode and a second electrode which is in contact with the electrolyte-containing medium. The method according to the invention is characterised in that the applied base shaped article possesses electrically conducting properties and that the contact between the shaped article and the anode is established by moving the article along the anode, at least part of the article being in contact with the anode. It has appeared that, in the method according to the invention, the shaped article does not adhere to the electrode so that the method may be practised continuously. A further advantage of the shaped article failing to adhere to the electrode is that the method according to the invention generates very little waste. Furthermore, it has appeared that the method according to the invention allows a shaped article to be produced with a very short polymerisation time, the electrically conductive polymer in which being homogeneously distributed. The applied base shaped article does not swell during wetting, so that the mechanical properties of the base shaped article do not deteriorate. As a result, if the method is applied, for instance, continuously, a higher rate of production can be applied. <IMAGE>
申请公布号 EP0587204(A1) 申请公布日期 1994.03.16
申请号 EP19930202025 申请日期 1993.07.09
申请人 DSM N.V. 发明人 VAN DIJK, HANS KLAAS;SCHELLEKENS, RONALD MICHAEL ALEXANDER MARIA
分类号 C08G61/12;(IPC1-7):C08G61/12 主分类号 C08G61/12
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