Porous polyethylene hollow fiber membrane of large pore diameter, production process thereof, and hydrophilized porous polyethylene hollow fiber membranes

摘要

PCT No. PCT/JP91/01638 Sec. 371 Date Jun. 9, 1992 Sec. 102(e) Date Jun. 9, 1992 PCT Filed Nov. 28, 1991 PCT Pub. No. WO92/09359 PCT Pub. Date Jun. 11, 1992.Disclosed is a porous polyethylene hollow fiber membrane of large pore diameter which have (a) rectangular pores formed by microfibrils that are oriented in the lengthwise direction of the fibers and joint portions that are composed of stacked lamellae, the pores being contiguous with each other from the inner wall surface to the outer wall surface of the hollow fiber membrane to form a stacked, multicellular structure, (b) an average pore diameter ranging from greater than 2 (my)m up to 10 (my)m as measured with a mercury porosimeter, (c) a porosity of 75 to 95%, and (d) an air permeability of not less than 8*105 l/m2*hr*0.5 atm. This hollow fiber membrane can be produced by melt-spinning polyethylene, annealing the resulting unstretched hollow fiber under specific conditions, and then cold-stretching and hot-stretching the annealed hollow fiber under specific conditions.