| 摘要 |
PURPOSE:To ionize oxygen, to pass the ionized oxygen through a solid electrolyte, to convert the ionized oxygen to an active oxygen species and to easily oxidize the reaction substrate. CONSTITUTION:A reactor 4 is divided into an oxygen supply chamber 2 and an oxidation reaction chamber 3 by a solid electrolyte 1 consisting of a fluorite- structure metal oxide such as ZrO2 contg. a solid soln. of Y2O3. Gaseous oxygen is supplied to the chamber 2, and a reaction substrate by a compd. consisting of a gas, a liq. or a fine-powder solid is supplied to the chamber 3. The reactor 4 is heated to 50-700 deg.C to convert the oxygen in the chamber 2 to oxygen ion, the ion is passed through the solid electrolyte 1 and converted to an active oxygen species which is supplied to the chamber 3, hence the reaction substrate in the chamber 3 easily reacts with the species in the absence of catalyst and electrode, and the gaseous, liq. or solid reaction substrate consisting of various compds. is oxidized with this simple device. |
