发明名称 |
SILVER-BASED CATALYST FOR VAPOR PHASE OXIDATION OF OLEFINS TO EPOXIDES |
摘要 |
This invention relates to a process of oxidizing an olefin having at least three carbon atoms directly to the corresponding epoxide comprising contacting the olefin with oxygen in the presence of a catalyst comprising a mixed silver-promoter metal (+2 or +3) silicate. In the direct oxidation of propylene the process yields a high selectivity to propylene oxide. This invention also relates to a catalyst and the process for preparing said catalyst. The process comprises contacting in an aqueous solution the dissolved salts (a) a silver-containing salt; (b) at least one salt containing a multivalent cation promoter; and (c) a silicon-containing salt, wherein the mole ratio of silicon to combined silver and promoter metals is at least 0.5, under conditions sufficient to form a mixed silver-promoter silicate precipitate. |
申请公布号 |
CA1327034(C) |
申请公布日期 |
1994.02.15 |
申请号 |
CA19880583760 |
申请日期 |
1988.11.22 |
申请人 |
DOW CHEMICAL COMPANY (THE) |
发明人 |
BOWMAN, ROBERT G. |
分类号 |
B01J23/48;B01J23/66;B01J27/25;C07B61/00;C07D301/10 |
主分类号 |
B01J23/48 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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