发明名称 |
INITIATED PEROXIDATION OF SECONDARY CARBON IN ALKANES AND CYCLOALKANES |
摘要 |
A secondary carbon atom in an alkane, including alkyl groups attached to aromatic rings, or cycloalkane is oxidized by molecular oxygen to the corresponding hydroperoxide in the absence of a catalyst. The oxidation is carried out in the presence of a tertiary hydroperoxide initiator which provides the free radicals needed to maintain the reaction. The amount of tertiary alcohol in the initiator is limited. |
申请公布号 |
WO9402458(A1) |
申请公布日期 |
1994.02.03 |
申请号 |
WO1993US05779 |
申请日期 |
1993.06.16 |
申请人 |
ABB LUMMUS CREST INC.;NITROCARBONO S.A. |
发明人 |
EMBER, GEORGE;DE CASTRO NETO, EDILBERTO, AUGUSTO;FRANCO, WILLIBALDO, ANEAS, JR. |
分类号 |
C07C409/04;C07C409/08;C07C409/14;(IPC1-7):C07C407/00 |
主分类号 |
C07C409/04 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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