发明名称 PROCESS FOR PREPARING POLYOLEFINS
摘要 A polyolefin is produced by polymerizing at least one olefin in the presence of a catalyst comprising the following ¢I! , ¢II! , and ¢III! : ¢I! a solid catalyst component prepared by reacting the reaction product prepared by reacting the following components (1), (2) and (3) in the presence of a compound represented by the general formula R3OH wherein R3 represents a hydrocarbon group having 6-20 carbon atoms which may contains a hetero atom such as oxygen, nitrogen, sulfur or chlorine with the following component (4): (1) a silicon oxide and/or an aluminum oxide; (2) a reaction product obtained by the reaction of a magnesium halide and a compound represented by the general formula Me(OR1)nXz-N wherein Me represents an element of Groups I to IV in the Periodic Table, z represents the valence of the element Me, n is O < n ? z, X is a halogen atom, and R1 is a hydrocarbon group having 1 to 20 carbon atoms; (3) a titanium compound represented by the general formula Ti(OR2)mX4 -m wherein R2 is a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen atom, and m is 0 ? m ? 4; and (4) an organoaluminum compound represented by the general formula Al(OR4),R54X3 - (p + q) wherein R4 and R5 are each a hydrocarbon group having 1-24 carbon atoms and may be same or different, X is a halogen atom or hydrogen atom and p and q are 0 ? p < 3, 0 ? q < 3, provided that 0 < p+q < 3; ¢II! a silicon compound having at least one bonding selected from Si-N-C and Si-O-C; and ¢III! an organometallic compound.
申请公布号 CA2099891(A1) 申请公布日期 1994.01.07
申请号 CA19932099891 申请日期 1993.07.06
申请人 NIPPON OIL COMPANY, LIMITED 发明人 SANO, AKIRA;SHIMIZU, HIROYUKI;MATSUURA, KAZUO
分类号 C08F4/646;C08F10/00;(IPC1-7):C08F10/00;C08F36/02 主分类号 C08F4/646
代理机构 代理人
主权项
地址