发明名称 |
Preparation of gold (I) mercaptides |
摘要 |
The known preparation of gold(I) mercaptides by means of reacting a gold(I) halogenide dialkyl sulfide complex, obtainable from a gold(III) halogenide or gold(III) halogen complex and a sulfide, with a mercaptan can be improved if a (C1- to C8-)-alkyl mercapto-(C3- to C6-) amino acid or a water-soluble salt thereof is used as organic sulfide. The advantages of the sulfides of the invention over the previously used sulfides reside in their water solubility and insolubility in solvents and therewith in a simplification of the purification of gold(I) mercaptides independently of their structure and solubility. A further advantage of alkyl mercapto amino acids, especially D,L methionine, is their odor, which is much less than that of the (C1-C8) alkyl sulfides previously used.
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申请公布号 |
US5252764(A) |
申请公布日期 |
1993.10.12 |
申请号 |
US19920984723 |
申请日期 |
1992.12.04 |
申请人 |
DEGUSSA AKTIENGESELLSCHAFT |
发明人 |
LOTZE, MARION;BAUER, MARGIT |
分类号 |
C07C319/02;C07C321/04;(IPC1-7):C07C321/04;C07C321/00 |
主分类号 |
C07C319/02 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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