发明名称 Process for producing optical active 4-hydroxy-2-cyclopentenone.
摘要 <p>A process for producing optically active 4-hydroxy-2-cyclopentenone [1] which comprises reacting 4-hydroxy-2-cyclopentenone represented by the formula: &lt;CHEM&gt; with an optically active propargyl alcohol derivative represented by the general formula: &lt;CHEM&gt; wherein R and R&lt;1&gt; each independently represent a halogenated phenyl group, an alkylphenyl group, or an alkyl group which may be substituted with one or more halogen atom(s), and * indicates an asymmetric carbon atom, to form an optically active complex [3] comprising an optically active 4-hydroxy-2-cyclopentenone represented by the formula [1] &lt;CHEM&gt; wherein * indicates an asymmetric carbon atom, and the optically active propargyl alcohol derivative [2], and then decomposing the optically active complex [3].</p>
申请公布号 EP0563636(A1) 申请公布日期 1993.10.06
申请号 EP19930103840 申请日期 1993.03.10
申请人 SUMITOMO CHEMICAL COMPANY, LIMITED 发明人 TODA, FUMIO;INOUE, YORIHIKO;MINAI, MASAYOSHI
分类号 C07B53/00;C07B57/00;C07C45/78;C07C45/85;C07C49/707 主分类号 C07B53/00
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