| 摘要 |
The thermal and oxidative stability of HVI-PAO olefin oligomers is improved by reaction of the oligomerization mixture conatining the olefin oligomer, dimer and isomerized but unoligomerized olefin with an aromatic compound, such as toluene, xylene or naphthalene. The reaction is carried out in the presence of an acidic catalyst, which may be heterogeneous solid catalyst such as an acidic clay or a crystalline zeolite such as MCM-22, a homogeneous Friedel-Crafts catalyst such as AlCl3, BF3 or their complexes or a supported catalyst such as AlCl3 on graphite or silica. The reaction improves the yield and thermal stability of the lube range products. The olefinic oligomer mixture which is reacted with the aromatic compound is prepared from 1-alkene oligomerization in contact with a reduced metal oxide, preferably reduced chromium oxide, catalyst on support such as silica. |
