发明名称 ALKYLATION OF POLYCYCLIC AROMATIC COMPOUNDS TO ALKYLATES ENRICHED IN THE PARA-SUBSTITUTED ISOMERS
摘要 Aromatic compounds, such as benzene or biphenyl, are alkylated with an alkylating agent, such as propylene, in the presence of an acidic mordenite zeolite catalyst under conditions sufficient to produce a mixture of substituted polycyclic aromatic compounds enriched in the para alkylated isomers, such as pdiisopropyl-benzene or p,p'-di(isopropyl)biphenyl, respectively. The novel acidic mordenite catalyst is characterized by its silica/alumina molar ratio, its porosity, and Symmetry Index. The p,p'-disubstituted isomers of aromatic compounds are useful as monomers in the preparation of thermotropic, liquid crystal polymers.
申请公布号 CA1322744(C) 申请公布日期 1993.10.05
申请号 CA19880583763 申请日期 1988.11.22
申请人 DOW CHEMICAL COMPANY (THE) 发明人 LEE, GUO-SHUH J.;ROCKE, STEPHEN C.;MAJ, JOSEPH J.
分类号 C07C39/17;B01J29/18;C07B31/00;C07B37/02;C07B37/04;C07B61/00;C07C1/00;C07C2/66;C07C2/86;C07C15/00;C07C17/00;C07C17/26;C07C17/266;C07C25/02;C07C25/13;C07C25/18;C07C27/00;C07C37/14;C07C41/00;C07C41/30;C07C43/205;C07C43/263;C07C67/00;C07C313/00;C07C319/12;C07C319/20;C07C321/24;C07C321/28;C07C323/20;C07C323/65 主分类号 C07C39/17
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