Method of preventing polymer scale deposition

摘要

A method of preventing polymer scale deposition in a polymerization vessel in polymerization of a particular monomer having an ethylenic double bond having a high dissolving power against the conventional scale preventive coatings, wherein said polymerization is carried out in a polymerization vessel of which the inner wall has been previously coated with a first coating solution comprising: (A) a water-soluble anionic dye, and (B) at least one member selected from the group consisting of inorganic colloids and cationic dyes, to form a first coating, and the first coating thus formed has been then coated with a second coating solution comprising: (C) an alkaline earth metal compound, and at least one member selected from the group consisting of: (D) a water-soluble anionic dye and (E) an inorganic colloid, to form a second coating. The polymerization vessel having the double coating as prepared above is also disclosed. Polymer scale deposition can be effectively prevented.