发明名称 |
PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS |
摘要 |
Process for the gas-phase polymerization of ethylene and ethylene mixtures with .alpha.-olefins CH2=CHR in the presence of a high activity catalyst comprising a titanium compound containing at least one Ti-halogen bond supported on magnesium dichloride in active form, said process comprising the steps of: (a) contacting the catalyst component; (b) prepolymerizing ethylene or ethylene mixtures with .alpha.-olefins in order to produce a polymer amount of from approximately 5 g per g of solid component, up to an amount corresponding to about 10% of the final catalyst yield; (c) polymerizing ethylene or ethylene mixtures with .alpha.-olefins in the gas-phase, in the presence of the prepolymer-catalyst system obtained in (b), while maintaining in the gas phase a molar concentration concentration of the alkane comprised between 20 and 90 % with respect to the total gases. (ZZ5072-ES-001)
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申请公布号 |
CA2087289(A1) |
申请公布日期 |
1993.09.14 |
申请号 |
CA19932087289 |
申请日期 |
1993.03.15 |
申请人 |
SPHERILENE S.R.L. |
发明人 |
COVEZZI, MASSIMO;GALLI, PAOLO;GOVONI, GABRIELE;RINALDI, ROBERTO |
分类号 |
C08F2/34;C08F4/60;C08F4/642;C08F4/654;C08F10/00;C08F10/02;(IPC1-7):C08F210/02 |
主分类号 |
C08F2/34 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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