发明名称 |
ELECTROCATALYTIC ASYMMETRIC DIHYDROXYLATION OF OLEFINIC COMPOUNDS |
摘要 |
2130564 9317150 PCTABS00025 A process is disclosed in wich optically active glycols are produced through an electrolytic asymmetric dihydroxylation (ADH) reaction involving olefins as substrates. The ADH reaction is mediated by a catalytically active amount of osmium tetroxide or osmium-containing precursor in a protic medium in the presence of chiral ligand. Any lower valent osmium species produced in the course of the ADH reaction is regnerated electrolytically either directly in the absence of a secondary oxidant or indirectly in the presence of a secondary oxidant that itself undergoes electrolytic regeneration. |
申请公布号 |
CA2130564(A1) |
申请公布日期 |
1993.09.02 |
申请号 |
CA19932130564 |
申请日期 |
1993.02.19 |
申请人 |
SEPRACOR INC |
发明人 |
GAO YUN;ZEPP CHARLES M |
分类号 |
B01J31/16;B01J31/18;B01J31/40;B01J37/34;C07C29/03;C07C29/48;C07C31/20;C07C31/42;C07C33/18;C07C33/20;C07C33/26;C07C33/30;C07C45/51;C07C49/497;C07C49/82;C07C67/31;C07C69/732;C25B3/02;(IPC1-7):C25B3/02 |
主分类号 |
B01J31/16 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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