发明名称 |
Purification of vinyl lactam polymers |
摘要 |
Vinylpyrrolidone and vinylcaprolactam residual monomers are removed from their respective crosslinked and non-crosslinked, vinyl lactam homopolymers, vinyl lactam copolymers and vinyl lactam terpolymers containing substantially contaminating amounts of residual vinylpyrrolidone or vinylcaprolactam monomer by a process which comprises (1) adjusting the pH of the vinyl lactam polymer slurry containing from about 1 to about 30 wt. % solids or a solution of the vinyl lactam polymer to a pH of less than 5 with an acid selected from the group of sulfuric, phosphoric, carbonic, formic and acetic acids and mixtures thereof; (2) reacting the acid with the residual vinyl lactam monomer at a temperature of from about 50 DEG to about 150 DEG C. for a period of from about 0.5 to about 10 hours until the residual monomer is reduced to less than 5 ppm and (3) drying said solids to a substantially pure vinyl lactam polymeric product in a free-flowing particulate state.
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申请公布号 |
US5239053(A) |
申请公布日期 |
1993.08.24 |
申请号 |
US19920834968 |
申请日期 |
1992.02.14 |
申请人 |
ISP INVESTMENTS INC. |
发明人 |
TSENG, SUSAN Y.;MANDELLA, WILLIAM L.;SMITH, TERRY E.;LOGIN, ROBERT B.;TAYLOR, PAUL D. |
分类号 |
C08F6/00 |
主分类号 |
C08F6/00 |
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