<p>Disclosed is a method of refining of a high purity steel capable of effectively lowering impurities in molten steel into respective ultra-low ranges. In secondary refining for molten steel after a molten iron prerefining process and a converting process, a reducing agent and a flux are added on the bath surface within a ladle containing the molten steel decarburized in a converter so that the composition of slag on the bath surface is adjusted in such a manner that the total concentration of FeO and MnO becomes 5wt% or less, and subsequently, impurities in the molten steel are effectively lowered into respective ultra-low ranges using a RH vacuum degassing unit. <IMAGE></p>
