| 摘要 |
Process for direct conversion of olefines to alcohols with an extra carbon atom compared with the olefine, by way of contact of an olefine, carbon monoxide and hydrogen with a catalyst suspended in an inert organic liquid means, whereby the catalyst may be defined as follows: (P-NC)(RhL3) formed by the association (adduced formation = adduct) of a complex of rhodium (RhL3) and an isonitryl function (P-NC) solid polymer, obtaining the polymer by copolymerisation of an omega-isocyano alkyl (C1-C1O) acrylate or metacrylate with a (met)acrylic or vinylic conomomer, in the presence of a polyfunctional reticulating monomer, or dehydrating the formamide precursor polymer obtained by way of copolymerisation of an alkyl formamide (C1-C10) acrylate or metacrylate with a (met)acrylic and/or vinylic comonomer, in the presence of the polyfunctional cross-linking monomer. The use of this catalyst allows the conversion of olefines to alcohols in a single operational stage and does not involve hydrogenation of the olefine, nor its isomerisation. |
