发明名称 Method for preparing tertiary hydrocarbon-silyl compounds.
摘要 <p>A method for preparing a tertiary hydrocarbon-silyl compound comprises the step of reacting a grignard reagent represented by the general formula: R&lt;1&gt;MgX&lt;1&gt; (wherein R&lt;1&gt; represents a tertiary hydrocarbon group and X&lt;1&gt; is a halogen atom) with a silicon atom-containing compound represented by the general formula: X&lt;2&gt;mR&lt;2&gt;nSiH4-m-n (wherein X&lt;2&gt; is a halogen atom and may be identical to or different from X&lt;1&gt;; R&lt;2&gt; is a monovalent hydrocarbon group; m is 1, 2 or 3; and n is 0, 1 or 2, provided that m+n is not more than 3 and that if n is 2, R&lt;2&gt;'s may be identical to or different from one another) in an aprotic inert organic solvent in the presence of a copper compound and/or a quaternary ammonium salt. According to this method, the tertiary hydrocarbon-silyl compounds can industrially efficiently and rapidly produced in high yields.</p>
申请公布号 EP0542250(A1) 申请公布日期 1993.05.19
申请号 EP19920119347 申请日期 1992.11.12
申请人 SHIN-ETSU CHEMICAL CO., LTD. 发明人 KUBOTA, TOHRU, SHIN-ETSU CHEMICAL CO.,LTD.;ISHIHARA, TOSHINOBU, SHIN-ETSU CHEMICAL CO.,LTD.;ENDO, MIKIO, SHIN-ETSU CHEMICAL CO.,LTD.
分类号 B01J27/122;B01J31/02;C07B61/00;C07F7/08;C07F7/12 主分类号 B01J27/122
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