发明名称 Process for the preparation of methacrylate esters.
摘要 The invention relates to a process for the preparation of methacrylate esters, wherein a propyne stream is isolated from a mixture of C<7>-hydrocarbons essentially consisting of propane, propene, propyne, propadiene and minor amounts of lower or higher carbon impurities, and said propyne stream is fed to a carbonylation unit and contacted therein with carbon monoxide and an alcohol in the presence of a carbonylation catalyst to form an alkyl methacrylate, characterized in that the mixture of C<7>-hydrocarbons is subjected to purification for essentially complete removal of hydrocarbon components having four or more carbon atoms. <IMAGE>
申请公布号 EP0539628(A1) 申请公布日期 1993.05.05
申请号 EP19910202814 申请日期 1991.10.30
申请人 SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. 发明人 HENGEVELD, JAN;DE BLANK, PETER BASTIAAN
分类号 C07C67/38;C07C69/54 主分类号 C07C67/38
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