Elimination of sulfide odor in thiocarbamate herbicides

摘要

It has now been discovered that the undesirable odor in thiocarbamate compounds can be suppressed or mostly eliminated by the process of this invention. Generally, the process of this invention involves mixing an aqueous solution of sodium hypochlorite, calcium hypochlorite or chloramine-B with the odorous thiocarbamate compound for a sufficient period of time, followed by a second step of mixing citric acid, maleic acid or oxalic acid with the treated thiocarbamate compound to eliminate chlorodialkylamine compounds produced in the first step.