VERSTAERKTE THERMOPLASTISCHE FORMMASSEN, VERFAHREN ZU DEREN HERSTELLUNG UND IHRE VERWENDUNG.

摘要

Reinforced thermoplastic moulding compsn. consists of (A) 40-94 (wt.) copolymer of (a1) 90-50% styrene (IA), alpha-methylstyrene (IB) and/or a ring alkyl-substd. styrene deriv. (IC) and (a2) 10-50% (meth)acrylonitrile (IIA) and/or methyl (meth)acrylate (IIB), (B) 20-0.5% terpolymer of (B1) 90-50% (I), (b2) 5-40% (II) and (b3) 2-30% of another monomer (III) and (C) 5-50% reinforcement (IV). The novelty is that (III) is t-butyl (meth)acrylate. The compsn. may also contain, w.r.t. A + B + C, (D) 1-50% graft copolymer(s) of (d1) 50-90% tubber(s) with Tg below 0 deg.C, (d2) 10-49% vinyl-aromatic monomer(s) with max. 12C atoms and (d3) 49-1% (IIA) and/or 1-8C-alkyl (meth)acrylate(s); and/or (E) up to 20% usual additives. The pref. compsn. is (A) 50-87% copolymer of 80-60% (I) and 20-40% (II), (B) 10-0.5% terpolymer of 90-50% (I), 5-40% (II) and 5-15% (III) and (C) 15-40% (IV); partic. (A) 55-65% copolymer of 80-20% (IA) and 20-40% acrylontrile (IIA-1), (B) 10-0.5% terpolymer of 85-60% (IA), (IIA-1) and 5-15% (III) and (C) 20-40% glass fibres.