HETEROCYCLISCHE NEOPHANANALOGA, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ALS SCHAEDLINGSBEKAEMPFUNGSMITTEL.

摘要

Neophanane analogues of formula (I) and their stereoisomers are new. In (I) A, B, C' and D = CH or N, but at least one must be N; X = CH2 or O; R1 = C-bound H; opt. substd. 1-4C alkyl; tri(1-4C)alkylsilyl; halo; NO2; CN, 2-6C alkenyl or alkynyl; amino; 3-7C cycloalkyl; phenyl; phenoxy; 1-5C alkoxy; 2-4C alkenyloxy or alkynyloxy; COOH; opt. substd. 1-4C alkylthio; 3-7C cycloalkoxy; 1-6C alkylcarbonyl; 1-4C alkoxycarbonyl; 2-4C alkenyloxycarbonyl; 3-5C alkynyloxycarbonyl; 1-3C haloalkoxy or haloalkylthio; substd. 1-4C alkoxy; 2-4C haloalkenyloxy; halo(1-4C)alkoxycarbonyl; halo (2-4C) alkenyloxycarbon yl; or di(1-6C)alkylamino, or two R1 gps. on adjacent C are together OCH2O, OCH2CH2O or 3-5C alkylene; R2 and R3 = 1-3C alkyl, 2-8C alkenyl, phenyl, or together an alkylene which, together with the quat. C atom, forms an opt. F-substd. 3-6 membered ring; R4 = H, F, CN, CCl3, CCH, 1-4C alkyl or CS.NH2; R5 = pyridyl, furyl, thienyl (all these opt. substd.), phthalimidyl, di(1-4C)alkylmaleinimidyl, thiophthalimidyl, di- or tetra-hydrophthalimidyl or substd. phenyl; or R4 and R5 can together complete opt. substd. indanyl, cyclopentenoyl or cyclopentenyl; n = 0-2.