| 摘要 |
2109845 9300373 PCTABS00019 Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula: --¢A!a--¢B!b--¢C!c-- wherein a represents about 1 to about 99 mole %; b represents about 0 to about 50 mole %; c represents about 1 to about 99 mole %; a + b + c is preferably about 100 %; A is (.alpha.); B is (.beta.); C is selected from the group consisting of (I), (II), and (III) combinations thereof, wherein D is OH, halide, OR4, NH2, NHR3, OM', or OM''; E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B; R1 represents proton, C1-C24 alkyl group, or C3-C24 cycloalkyl; R2 represents C1-C24 alkylene group, C3-C24 cycloalkylene, C6-C18 arylene, or C7-C30 alkylarylene; R3 represents C1-C24 alkyl, C3-C24 cycloalkyl, C1-C24 aryl, or C7-C30 alkylaryl; R4 represents C1-C24 alkyl, C3-C24 cycloalkyl, C1-C24 aryl, or C7-C30 alkylaryl; M' represents alkali metal; M'' represents alkaline-earth metal. Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
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